I'm not sure if you mean
"create an imaginary situation in Celestia that shows planets lined up"
or
"set Celestia to a date when many planets are almost aligned"
A date when many planets were aligned was May 5, 2000.
Run Celestia
Open the menu "Time"
Select the entry "Set Time"
type 5 in the day field
type 5 in the month field
type 2000 in the year field
Select the "OK" button
Change your viewpoint and Render options to see how they look.
Here's a view from far above the Sun.
(click on this picture to see a much larger version)
[edit]
A similar alignment happened on September 2nd, 1861.
Setting Celestia's time and viewing it is left as an exercise for the reader
See
http://drumright.ossm.edu/astronomy/conjunctions.html
for more information.
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