Although there are more extremes such as the cold, in a psyiological sense what would happen to the body is a very exagerated version of 'the bends', something divers experience if they have been at depth for a long time and come to the surface without allowing the increased pressure of gas in their body to release gradually at each depth as they ascend.
The degree of injury and permanent damage is dependant on how deep you were, and how quickly you ascended.
As you (stupidly) exit the space craft you could liken it to a diver surfacing from great depth to the surface in an instant!
Obviously you will die very quickly.
But soft tissue damage in the brain and other areas makes it very unlikely that you would be 'the same' after even a short exposure to *real* space. Scenes from all movies to date are very very innacurate. With the suprising exception of the scene at the end of 'Total Recall' which is, how should I put it, *interesting*!
The freezing as air rushes out of your lungs would also, as others have said cool and eventually (in a very short period) freeze you from the inside out in your airways. This would be very hard to reverse even if you 'shot straight back into another air lock'!
Also, if you were stupid enough to hold your breath you would rupture, and potentially (I guess) explode in a very small organic sort of way. More like a silent pop in space. By that time you would be pretty much flash frozen anyway.. So you might sort of crack and pop at the same time.
The holding your breath thing can happen in diving as well, actually very easilly in the top couple of meters (as that is where the biggest change in pressure is) if you hold your breath while ascending.
So, what to do?
Hold your breath - Rupture.
Don't hold your breath - Freeze your airways.
Either way - You will freeze and suffocate.
How about.. Stay in the spaceship!